Product ID:M/M DOUBLE DUTY BLOCKS, T270
MSDS Date:09/22/1993
FSC:6850
NIIN:00N072661
MSDS Number: CBYRQ

NATIONAL CHEMSEARCH

HOUSTON, TX 75015
US

Emergency Phone: 214-438-1381

Info Phone: 214-438-1381

Preparer: L. DEYOUNG

Cage: 0TTE8

NATIONAL CHEMSEARCH

IRVING, TX 75015 US

Telephone: 214-438-4144

Cage: 0TTE8

BENZENE, P-DICHLORO-; (P-DICHLOROBENZENE) (SARA 313)

CAS: 106-46-7

RTECS: CZ4550000

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BODY WT, SOME ORGAN WTS & CLINICAL PARAMETERS,

RTECS: 9999999ZZ

CHANGES IN BONE MARROW, SPLEEN, THYMUS & NASAL

RTECS: 9999999ZZ

PRODUCED SOME DEATHS.

RTECS: 9999999ZZ

SURF OF EYES & LIDS W/WATER. GET IMMED MED

RTECS: 9999999ZZ

WATER & SOAP IF AVAIL FOR 15 MIN. REMOVE CONTAMD

RTECS: 9999999ZZ

GIVE 3 TO 4 GLASSES OF

RTECS: 9999999ZZ

FLUIDS AGAIN. GET MED ATTN TO DETERMINE WHETHER

RTECS: 9999999ZZ

ANYTHING BY MOUTH TO AN UNCON OR CONVULSING PERSON.

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CAUSES EYE IRRIT. CAUSES SKIN
IRRIT & BURNING SENSATIONS. INHAL CAN CAUSE NASAL & RESP TRACT
IRRIT. INGEST MAY BE HARMFUL & MAY CAUSE NAUS & VOMIT. CHRONIC:
EXTENDED/PRLNGD INHAL MAY CAUSE HDCH, SWELL AROUND EYES, INFLAM OF
MUC MEMBSOF NOSE, LOSS OF APPETITE, NAUS OR VOMIT & POSS LIVER &
KIDNEY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE, P-DICHLORO: IARC MONOGRAPHS,
SUPP, VOL 7, PG 192, 1987:GROUP 2B. NTP 7TH ANNUAL REPORT ON
CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ: DMG. INGEST IN HIGH DOSES MAY CAUSE
LIVER & KIDNEY INJURY & JAUNDICE. TARGET ORGANS: LIVER & KIDNEY.
RPTD INHAL STUDIES (UP TO 14 WEEKS) W/P-DICHLOROBENZENE CONDUCTED
IN RATS, RABBITS, GUINE A PIGS & DOGS HAVE RSLTD IN LIVER & KIDNEY
TOX, LUNG EFTS, REVERSIBLE EYE CHANGES (RABBITS ONLY), REDUCED BODY
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE FROM AREA TO FRESH AIR. IF NOT BRTHG, CLEAR
AIRWAY & START MOUTH-TO-MOUTH ARTF RESP OR USE BAG-MASK RESP. GET
IMMED MED ATTN. IF VICTIM IS HAVING TROUBLE BRTHG, TRANSPORT TO MED
CARE & I F AVAIL GIVE SUPPLEMENTAL OXYGEN. EYES:IMMED RINSE
W/WATER. REMOVE ANY CONTACT LENSES & CONTINUE FLUSHING W/RUNNING
WATER FOR AT LEAST 15 MIN. HOLD EYELIDS APART TO ENSURE RINSING OF
ENTIRE (ING 5)

Flash Point Method:TCC
Flash Point:150F,66C
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:UPON BURNING, MAY FORM OXIDES OF CARBON,
CHLORIDES AND CHLORINE GAS.

Spill Release Procedures:MATERIAL CONSISTS OF A SOLID BLOCK WRAPPED IN
PROTECTIVE PLASTIC TO PREVENT SUBLIMATION. IF MATERIAL BREAKS OR IS
SCATTERED, SWEEP UP AND PUT IN A LABELED CONTAINER FOR PROPER
DISPOSAL.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:DO NOT USE OR STORE NEAR HEAT OR OPEN
FLAME. STORE AT MODERATE TEMPERATURES, IN A WELL-VENTILATED AREA.
WASH THOROUGHLY AFTER HANDLING.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL
BEFORE USING THIS PRODUCT.

Respiratory Protection:FOR EMERGENCIES OR WORK IN CONFINED AREAS, WEAR
NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR
RESPIRATORY PROTECTION.
Ventilation:GENERAL OR MECHANICAL EXHAUST TO MAINTAIN EXPOSURE LEVELS
BELOW TLV.
Protective Gloves:PVC GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN: 1994:ANTIC TO BE CARCIN. ANIMAL:KIDNEY, BLADDER,
URETER, LIVER. EFTS OF OVEREXP: WT & NUMBER OF WHITE BLOOD CELLS,
CLINICAL SIGNS & ANIMAL DEATHS AT HIGH EXPOS LEVELS WHILE NO EFTS R
EPORTED IN MICE/MONKEYS. NO ADVERSE EFTS OBSERVED IN RATS FOLLOWING
RPTD SKIN EXPOS BUT EXHIBITED CHANGES IN (ING 2)

Boiling Pt:B.P. Text:345F,174C
Vapor Pres:0.6
Vapor Density:5.1
Spec Gravity:1.458 (H*2O=1)
Evaporation Rate & Reference:0.15 (BU A/C=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLUE, OPAQUE SOLID; CHERRY/MOTHBALL ODOR.
Percent Volatiles by Volume:99

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT, HOT SURFACES, SPARKS AND OPEN FLAME.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
CHLORIDES, CHLORINE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH STATE, FEDERAL AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.